Graphene material: Thin sheet stronger than diamond


     Graphene has been produced unintentionally in small quantities for centuries through the use of pencils and other similar graphite applications. It was observed originally in electron microscope in 1962, but it was studied only while supported on metal surfaces. The Graphene material was later rediscovered,isolated, and characterized in 2004 by Andre Geim amd konstantin Novoselov at the University of Manchester.

     Graphene is an allotrope of carbon consisting of a single layer of carbon atom arrange in a hexagonal lattice. It is a basic structural element of many other allotropes of carbon, such as graphite, diamond, charcoal, carbon nano-tubes and fullerens.

>Properties of Graphene:


1. Electronic properties:

     It is one of the best electrical conductors on Earth. The unique atomic arrangement of the carbon atoms in graphene allows its electrons to easily travel at extremely high velocity without the significant chance of scattering, saving precious energy typically lost in other conductors.


     Scientists have found that graphene remains capable of conducting electricity even at the limit of nominally zero carrier concentration because the electrons don't seem to slow down or localize. The electrons moving around carbon atoms interact with the periodic potential of graphene's honeycomb lattice, which gives rise to new quasiparticles that have lost their mass, or rest mass (so-called massless Dirac fermions). That means that graphene never stops conducting. It was also found that they travel far faster than electrons in other semiconductors.

2. Mechanical properties:


     The impressive intrinsic mechanical properties of graphene, its stiffness, strength and toughness, are one of the reasons that make graphene stand out both as an individual material and as a reinforcing agent in composites. They are caused by the stability of the SP2 bonds that form the hexagonal lattice and oppose a variety of in-plane deformations.

3. Stiffness:


     The breaking force obtained experimentally and from simulation was almost identical and the experimental value of the second order elastic stiffness was equal to 340 ± 50 N m-1. This value corresponds to a Young's modulus of 1.0 ± 0.1TPa, assuming an effective thickness of 0.335nm.

4. Strength:


     Defect-free, mono-layer graphene is considered to be the strongest material ever tested with a strength of 42 N m-1, which equates to an intrinsic strength of 130GPa.

5. Toughness:


     Fracture toughness, which is a property very relevant to engineering applications, is one of the most important mechanical properties of graphene and was measured as a critical stress intensity factor of 4.0 ±0.6MPa.

>Methods to prepare Graphene are:


1. Micro mechanical cleavage
2. Chemical Vapor Deposition (CVD)
3. Epitaxial growth on SiC substrates
4. chemical reduction of exfoliated graphene oxide
5. Liquid phase exfoliation (LPE) of graphite
6. Unzipping of carbon nano-tubes.

>Some applications of graphene are:


1. Energy storage and solar cells:


     Graphene-based nano-materials have many promising applications in energy-related areas. Just some recent examples: Graphene improves both energy capacity and charge rate in rechargeable batteries; activated graphene makes superior super capacitors for energy storage; graphene electrodes may lead to a promising approach for making solar cells that are inexpensive, lightweight and flexible; and multi-functional graphene mats are promising substrates for catalytic systems.
These examples highlight the four major energy-related areas where graphene will have an impact: solar cells, super capacitors, graphene batteries, and catalysis for fuel cells.

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2. Sensor applications:


     Functionalized graphene holds exceptional promise for biological and chemical sensors. Already, researchers have shown that the distinctive 2 D structure of graphene oxide (GO), combined with its super permeability to water molecules, leads to sensing devices with an unprecedented speed.
Researchers also have begun to work with graphene foams – three-dimensional structures of interconnected graphene sheets with extremely high conductivity. These structures are very promising as gas sensors and as biosensors to detect diseases.

3. Electronics applications:



     Graphene has a unique combination of properties that is ideal for next-generation electronics, including mechanical flexibility, high electrical conductivity, and chemical stability. Combine this with inkjet printing and you get an inexpensive and scalable path for exploiting these properties in real-world technologies.

4. Transistors and memory:

     Some of the most promising applications of graphene are in electronics (as transistors and interconnects), detectors (as sensor elements) and thermal management (as lateral heat spreaders). The first graphene field-effect transistors (FETs) – with both bottom and top gates – have already been demonstrated. At the same time, for any transistor to be useful for analog communication or digital applications, the level of the electronic low-frequency noise has to be decreased to an acceptable level.

     Transistors on the basis of graphene are considered to be potential successors for the some silicon components currently in use. Due to the fact that an electron can move faster through graphene than through silicon, the material shows potential to enable terahertz computing.

     In the ultimate nano-scale transistor – dubbed a ballistic transistor – the electrons avoid collisions, i.e. there is a virtually unimpeded flow of current. Ballistic conduction would enable incredibly fast switching devices. Graphene has the potential to enable ballistic transistors at room temperature.

5. Flexible, stretchable and foldable electronics:


     Flexible electronics relies on bendable substrates and truly foldable electronics requires a foldable substrate with a very stable conductor that can withstand folding (i.e. an edge in the substrate at the point of the fold, which develops creases, and the deformation remains even after unfolding).

     That means that, in addition to a foldable substrate like paper, the conductor that is deposited on this substrate also needs to be foldable. To that end, researchers have demonstrated a fabrication process for foldable graphene circuits based on paper substrates.Companies like Samsung, LG, Lenovo and many more are in the race to develops foldable screen or foldable smartphone.

     Scientists have devised a chemical vapor deposition (CVD) method for turning graphene sheets into porous three-dimensional foams with extremely high conductivity. By permeating this foam with a siloxane-based polymer, the researchers have produced a composite that can be twisted, stretched and bent without harming its electrical or mechanical properties.

6. Photodetectors:


     Researchers have demonstrated that graphene can be used for telecommunications applications and that its weak and universal optical response might be turned into advantages for ultra fast photonics applications. They also found that graphene could be potentially exploited as a saturable absorber with wide optical response ranging from ultra-violet, visible, infrared to terahertz.

     There is a very strong research interest in using graphene for applications in optoelectronics. Graphene-based photo detectors have been realized before and graphene's suitability for high bandwidth photo detection has been demonstrated in a 10GBit/s optical data link.

7. Coatings:


     Coating objects with graphene can serve different purposed. For instance, researchers have now shown that it is possible to use graphene sheets to create a super hydrophobic coating material that shows stable super hydrophobicity under both static as well as dynamic (droplet impact) conditions, thereby forming extremely water repelling structures.

     Graphene also is the world's thinnest known coating for protecting metals against corrosion. It was found that graphene, whether made directly on copper or nickel or transferred onto another metal, provides protection against corrosion.Researchers demonstrated the use of graphene as a transparent conductive coating for photonic devices and show that its high transparency and low resistivity make this two-dimensional crystal ideally suitable for electrodes in liquid crystal devices (LCDs).

     Since graphene is light, hard and transparent material rather than using screen protector or tempered glass or any gorilla glass protection graphene coating can be used to protect smartphone, computers and laptop screens.

8. Biotechnology and medicine:


     Recent research also points to an opportunity to replacing antibiotics with graphene based photo thermal agents to trap and kill bacteria.

     In the decades-old quest to build artificial muscles, many materials have been investigated with regard to their suitability for actuator application (actuation is the ability of a material to reversibly change dimensions under the influence of various stimuli). Besides artificial muscles, potential applications include Micro Electro Mechanical Systems (MEMS), biomimetic micro and nano-robots, and micro fluidic devices. In experiments, scientists have shown that graphene nano ribbons can provide actuation.

9. Radiation shielding:


     Graphene appears to be a most effective material for electromagnetic interference (EMI) shielding. Experiments suggests the feasibility of manufacturing an ultra thin, transparent, weightless, and flexible EMI shield by a single or a few atomic layers of graphene.

10. Thermal management:


     This is where graphene comes in – it conducts heat better than any other known material. Thermal interface materials (TIMs) are essential ingredients of thermal management and researchers have achieved a record enhancement of the thermal conductivity of TIMs by addition of an optimized mixture of graphene and multi-layer graphene.

11. Water purification:


     A new method of purifying brackish water is Capacitive De-Ionization (CDI) technology. The advantages of CDI are that it has no secondary pollution, is cost-effective and energy efficient. Researchers have developed a CDI application that uses graphene-like nano-flakes as electrodes for capacitive deionization. They found that the graphene electrodes resulted in a better CDI performance than the conventionally used activated carbon materials.
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